Monitoring For Elemental Composition Of Particulate Matter Deposited In Snow Cover Around Coal-Fired Thermal Power Plant (Karaganda, Central Kazakhstan).
https://doi.org/10.24057/2071-9388-2023-2829
Abstract
Studies on thermal power plant areas with respect to chemical composition of particulate matter deposited in snow cover are limited. This study aims to monitor (2014–2022) particulate load and trace elements associated with the particulate matter distributed around (0.5-4.5 km) the coal-fired thermal power plant in Karaganda. In this study, snow cover was used as an effective scavenger of atmospheric pollutants. Using instrumental neutron activation analysis and atomic absorption spectrometry, the content of 26 elements and Hg, respectively, was determined in the particulate phase of snow. The results showed that particulate load varied from 26 to 1751, with mean of 427 and a background of 47 mg m-2 d-1. Anthropogenic impact caused a significant increase in content of U, Hg, Ta, Zn, Na, Cr, Co, Sr, Rb, Cs, Sc, Ca, Fe, Nd, Ba (2–30 times) in the samples compared to the background. Metal-bearing phases of Zn, Ba, As, U-Ta-Nb were detected through scanning electron microscope. The highest levels of particulate load (169–1032 mg m-2 d-1) and element contents in the samples were localized up to 0.7 km from the thermal power plant. The changes of particulate load and element composition of snow deposits during the monitoring period were connected with temperature, modernization of dust-collecting equipment, composition of coal and fly ash, long-range transport of emissions from other industries. The element content and metal-bearing phases in the particulate phase of snow can be used as markers for identifying emission sources from coal combustion.
Keywords
urban snow pollution,
rare elements,
heavy metals,
metal-bearing phases,
atmospheric deposition,
coal combustion
Supporting agencies: The experimental procedures were carried out at Tomsk Polytechnic University within the framework of Tomsk Polytechnic University Competitiveness Enhancement Program Grant in the Group of Top Level World Research and Academic Institutions. This work was performed on the unique scientific IRT-T equipment. The authors thank Alexander Sudyko and Larisa Bagydskaya for the performing of instrumental neutron activation analysis, Ekaterina Filimonenko and Nina Osipova for their help in Hg measurements in the Uranium Geology International Centre (Tomsk Polytechnic University), Natalia Savelyevna for her assistance in SEM-EDX analysis (Karaganda State Technical University).
About the Authors
A. V. Talovskaya
National Research Tomsk Polytechnic University
Russian Federation
Russian Federation
30 Lenin Ave., 634050, Tomsk
T. E. Adil’bayeva
National Research Tomsk Polytechnic University
Russian Federation
Russian Federation
30 Lenin Ave., 634050, Tomsk
E. G. Yazikov
National Research Tomsk Polytechnic University
Russian Federation
Russian Federation
30 Lenin Ave., 634050, Tomsk
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For citations:
Talovskaya A.V., Adil’bayeva T.E., Yazikov E.G. Monitoring For Elemental Composition Of Particulate Matter Deposited In Snow Cover Around Coal-Fired Thermal Power Plant (Karaganda, Central Kazakhstan). GEOGRAPHY, ENVIRONMENT, SUSTAINABILITY. 2023;16(4):180-192. https://doi.org/10.24057/2071-9388-2023-2829
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