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Physicochemical Properties of Road Dust in Moscow

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Road dust is a composite substance formed due to wear of different components of transport infrastructure and motor vehicles. In 2017, 214 road dust samples were collected in Moscow to analyze pH, electrical conductivity (EC), and organic carbon (Cоrg) content that controls the ability of dust to fix pollutants. The road dust was dominated by sand and silt size particles (the share of PM10 particles varies from 2.3% to 39%) and had alkaline pH (6.4–8.1), high EC (33–712 μS/cm) and Cоrg (0.17–6.7%). The road dust is alkalinized by detergents and particles formed by abrasion of roadways and blown out from construction sites. A three-fold excess of the EC over the background values (dust in parks) is mainly due to the use of the de-icing agents and roadway maintenance. But the concentration of Cоrg in the Moscow’s road dust is on average 2 times lower compared to the background values; the increased content of Cоrg in the courtyards is associated with the application of organic fertilizers. The most significant factor that determines the physicochemical properties of the dust was the type of a road. The dust on large roads including the Third Ring Road had higher pH (7.0–8.0) and EC (98–712 μS/ cm); it contained higher proportions of the fine particle-size fractions compared to other roads. The Cоrg content in the road dust was minimum on Moscow’s major radial highways due to the insignificant contribution of soil particles. The spatial trends in variability of the physicochemical properties of the dust in Moscow were not evident as they were to a large extent masked by other factors: proximity to industrial zones and large forest parks, differences in the de-icing agents used, unequal frequencies of road cleaning, and the various contribution of soil particles that vary in composition and genesis in different parts of Moscow.

About the Authors

Nikolay S. Kasimov
Lomonosov Moscow State University
Russian Federation

Leninskie gory 1, Moscow, 119991

Natalia E. Kosheleva
Lomonosov Moscow State University
Russian Federation

Leninskie gory 1, Moscow, 119991

Dmitry V. Vlasov
Lomonosov Moscow State University
Russian Federation

Leninskie gory 1, Moscow, 119991

Ksenia S. Nabelkina
Lomonosov Moscow State University
Russian Federation

Leninskie gory 1, Moscow, 119991

Alexander V. Ryzhov
Lomonosov Moscow State University
Russian Federation

Leninskie gory 1, Moscow, 119991


1. Achkasov A., Basharkevich I., Varava K. and Samaev S. (2006). Pollution of snow cover under the influence of deicing agents. Exploration and protection of mineral resources, 9-10, pp. 132-137 (in Russian).

2. Acosta J., Faz A., Kalbitz K., Jansen B. and Martinez-Martinez S. (2011). Heavy metal concentrations in particle size fractions from street dust of Murcia (Spain) as the basis for risk assessment. Journal of Environmental Monitoring, 13, pp. 3087-3096. DOI: 10.1039/C1EM10364D

3. Al-Khashman O. (2007). Determination of metal accumulation in deposited street dusts in Amman, Jordan. Environmental Geochemistry and Health, 29, pp. 1-10. DOI: 10.1007/s10653-006-9067-8

4. Belis C., Karagulian F., Larsen B. and Hopke P. (2013). Critical review and meta-analysis of ambient particulate matter source apportionment using receptor models in Europe. Atmospheric Environment, 69, pp. 94-108. DOI: 10.1016/j.atmosenv.2012.11.009

5. Bityukova V. and Saulskaya T. (2017). Changes of the anthropogenic impact of Moscow industrial zones during the recent decades. Vestnik Moskovskogo Unviersiteta, Seriya Geografiya, 3, pp. 24-33 (in Russian with English summary).

6. Bityukova V., Vlasov D., Dorokhova M., Kasimov N., Kislyakova N., Kirillov P., Kosheleva N., Nikiforova E., Petukhova N., Ryzhov A., Savoskul M., Saulskaya T. and Shartova N. (2016). East – West of Moscow: a spatial analysis of social and environmental issues. Moscow: Faculty of Geography, Lomonosov Moscow State University (in Russian with English summary).

7. Da Costa D. and Oliveira D. (2009). Natural organic matter in atmospheric particles. In: Biophysico-chemical processes involving natural nonliving organic matter in environmental systems. New York: Wiley, pp. 451-485.

8. Demetriades A. and Birke M. (2015). Urban geochemical mapping manual: sampling, sample preparation, laboratory analysis, quality control check, statistical processing and map plotting. Brussels: EuroGeoSurveys.

9. Diapouli E., Manousakas M., Vratolis S., Vasilatou V., Maggos Th., Saraga D., Grigoratos Th., Argyropoulos G., Voutsa D., Samara C. and Eleftheriadis K. (2017). Evolution of air pollution source contributions over one decade, derived by PM 10 and PM 2.5 source apportionment in two metropolitan urban areas in Greece. Atmospheric Environment, 164, pp. 416-430. DOI: 10.1016/j.atmosenv.2017.06.016

10. Faure P., Landais P., Schlepp L. and Michels R. (2000). Evidence for diffuse contamination of river sediments by road asphalt particles. Environmental Science & Technology, 34, pp. 1174-1181. DOI: 10.1021/es9909733

11. Fonova S. (2017). Scientific and methodological apparatus for assessing the geoecological risk of contamination by heavy metals in the area of roads of the first category. Ph.D. Thesis. Voronezh (in Russian).

12. Garg B., Cadle S., Mulawa P., Groblicki P., Laroo C. and Parr G. (2000). Brake wear particulate matter emissions. Environmental Science & Technology, 34, pp. 4463-4469. DOI: 10.1021/es001108h

13. Gendugov V. and Glazunov G. (2007). Wind erosion and dusting of air. Moscow: Fizmatlit (in Russian).

14. Greinert A., Fruzińska R. and Kostecki J. (2013). Urban soils in Zielona Gόra. In: P. Charzyński, P. Hulisz and R. Bednarek, eds., Technogenic soils of Poland. Toruń: Polish Society of Soil Science, pp. 31-54.

15. Grigoriev V. and Kissel A. (2002). Handbook of methods and technical means of reducing emissions of pollutants into the atmosphere, used in the development of the draft MPE regulations. St. Petersburg: Atmosphere Research Institute (in Russian).

16. Hu X., Zhang Y., Luo J., Wang T., Lian H. and Ding. Z. (2011). Bioaccessibility and health risk of arsenic, mercury and other metals in urban street dusts from a mega-city, Nanjing, China. Environmental Pollution, 159, pp. 1215-1221. DOI: 10.1016/j.envpol.2011.01.037

17. Jayarathne A., Egodawatta P., Ayoko G. and Goonetilleke A. (2017). Geochemical phase and particle size relationships of metals in urban road dust. Environmental Pollution, 230, pp. 218-226. DOI: 10.1016/j.envpol.2017.06.059

18. Kasimov N., Kosheleva N., Vlasov D. and Terskaya E. (2012). Geochemistry of snow cover within the Eastern district of Moscow. Vestnik Moskovskogo Unviersiteta, Seriya Geografiya, 4, pp. 14-24 (in Russian with English summary).

19. Kasimov N., Vlasov D., Kosheleva N. and Nikiforova E. (2016). Landscape geochemistry of Eastern Moscow. Moscow: APR (in Russian).

20. Kasimov N., Kosheleva N., Nikiforova E. and Vlasov D. (2017). Benzo[a]pyrene in urban environments of eastern Moscow: pollution levels and critical loads. Atmospheric Chemistry and Physics. 2017, 17, pp. 2217-2227. DOI: 10.5194/acp-17-2217-2017

21. Khomyakov D. (2015). Moscow does not believe in salt. About deicing agents used in Moscow for the winter period, and their volume. Road Empire, 58, pp. 91-95 (in Russian).

22. Khusnullin M. (2013). The current state of the backbone of the street-road network [online] Urban Planning: The Transport Aspect. Russian and international experience. Available at: [Accessed 04 July 2017] (in Russian).

23. Kosheleva N., Kasimov N. and Vlasov D. (2015). Factors of the accumulation of heavy metals and metalloids at geochemical barriers in urban soils. Eurasian Soil Science, 5(48), pp. 476-492. DOI: 10.1134/S1064229315050038

24. Kosheleva N., Dorokhova M., Kuzminskaya N., Ryzhov A. and Kasimov N. (2018a). Impact of motor vehicles on the ecological state of soils in the Western District of Moscow. Vestnik Moskovskogo Unviersiteta, Seriya Geografiya, 2, pp. 16-27 (in Russian with English summary).

25. Kosheleva N., Vlasov D., Korlyakov I. and Kasimov N. (2018b). Сontamination of urban soils with heavy metals in Moscow as affected by building development. Science of the Total Environment, 636, pp. 854-863. DOI: 10.1016/j.scitotenv.2018.04.308

26. Ladonin D. (2016). Forms of heavy metal compounds in technogenically polluted soils. Dr. of Biological Sciences Thesis, Moscow (in Russian).

27. Ladonin D. and Plyaskina O. (2009). Isotopic composition of lead in soils and street dust in the Southeastern administrative district of Moscow. Eurasian Soil Science, 1(42), pp. 93-104. DOI: 10.1134/S1064229309010128

28. Lawrence S., Sokhi R. and Ravindra K. (2016). Quantification of vehicle fleet PM 10 particulate matter emission factors from exhaust and non-exhaust sources using tunnel measurement techniques. Environmental Pollution, 210, pp. 419-428. DOI: 10.1016/j.envpol.2016.01.011

29. Lodygin E., Chukov S., Beznosikov V. and Gabov D. (2008). Polycyclic aromatic hydrocarbons in soils of Vasilievsky Island (St. Petersburg). Eurasian Soil Science, 12(41), pp. 1321-1326. DOI: 10.1134/S1064229308120107

30. Lokoshchenko M. (2015). Wind direction in Moscow. Russian Meteorology and Hydrology, 10(40), pp. 639-646. DOI: 10.3103/S1068373915100015

31. National Emissions Inventory. (2017). United States Environmental Protection Agency. [online]. Available at: [Accessed 21 October 2017]

32. Nazzal Y., Rosen M. and Al-Rawabdeh A. (2013). Assessment of metal pollution in urban road dusts from selected highways of the Greater Toronto Area in Canada. Environmental Monitoring and Assessment, 185, pp. 1847-1858. DOI: 10.1007/s10661-012-2672-3

33. Nikiforova E., Kosheleva N. and Khaibrakhmanov T. (2016). Ecological impact of antiglaze treatment on soils of the Eastern district of Moscow. Vestnik Moskovskogo Unviersiteta, Seriya Geografiya, 3, pp. 40-49 (in Russian with English summary).

34. Privalenko V. and Bezuglova O. (2003). Ecological problems of anthropogenic landscapes of the Rostov region. Rostov-on-Don: Publishing House of North Caucasus Higher School Research Center (in Russian).

35. Prokofieva T. and Stroganova M. (2004). Soils of Moscow (soils in the urban environment, their features and ecological significance). Moscow: GEOS (in Russian).

36. Prokofieva T., Rozanova M. and Poputnikov V. (2013). Some features of soil organic matter in parks and adjacent residential areas of Moscow. Eurasian Soil Science, 3(46), pp. 273-283. DOI: 10.1134/S1064229313030071

37. Prokofieva T, Shishkov V., Kiryushin A. and Kalushin I. (2015). Properties of atmospheric solid fallouts in roadside areas of Moscow. Izvestiya Rossiiskoi akademii nauk, Seriya geograficheskaya, 3, pp. 107-120 (in Russian with English summary).

38. Report on the State of the Environment in the City of Moscow in 2016. Edited by Kulbachevsky A. (2017). Moscow: Department for Environmental Management and Protection; Institute of Urban Planning and System Design (in Russian).

39. Rozanova M., Prokofieva T., Lysak L. and Rakhleeva A. (2016). Soil organic matter in the Moscow State University botanical garden on the Leninskie Gori. Eurasian Soil Science, 9(49), p. 1013-1025. DOI: 10.1134/S106422931609012X

40. Sister V. and Koretsky V. (2004). Engineering-environmental protection of water system of the northern megapolis in winter period. Moscow: Center MSUIE (in Russian).

41. Sutherland R., Tack F. and Ziegler A. (2012). Road-deposited sediments in an urban environment: A first look at sequentially extracted element loads in grain size fractions. Journal of Hazardous Materials, 225-226, pp. 54-62. DOI: 10.1016/j.jhazmat.2012.04.066

42. Tager I. (2005). Health effects of aerosols: Mechanisms and epidemiology. In: Aerosols Handbook: Measurement, dosimetry, and health effects. Boca Raton: CRC Press, pp. 619-696.

43. Tikunov V. (1997). Modeling in cartography. Moscow: Publishing House of Moscow State University (in Russian).

44. Vlasov D. (2017). Metals and metalloids in PM 10 fraction of the road dust of Eastern Moscow. RUDN Journal of Ecology and Life Safety, 4(25), pp. 529-539. DOI: 10.22363/2313-2310-2017-25-4-529-539 (in Russian with English summary).

45. Vlasov D., Kasimov N. and Kosheleva N. (2015). Geochemistry of the road dust in the Eastern district of Moscow. Vestnik Moskovskogo Unviersiteta, Seriya Geografiya, 1, pp. 23-33 (in Russian with English summary).

46. Vodyanitskii Yu. (2008). The affinity of heavy metals and metalloids to carrier phases in soils. Agrochemistry, 9, pp. 87-94 (in Russian with English summary).

47. Vodyanitskii Yu. (2015). Organic matter of urban soils: A review. Eurasian Soil Science, 8(48), pp. 802-811.

48. Wang X. and Qin Y. (2007). Leaching characteristics of heavy metals and As from two urban roadside soils. Environmental Monitoring and Assessment, 132, pp. 83-92. DOI: 10.1007/s10661-006-9504-2

49. Weather and Climate. (2017). Reference Information Portal “Weather and Climate”. [online]. Available at: [Accessed 21 July 2017] (in Russian).

50. Weckwerth G. (2001). Verification of traffic emitted aerosol components in the ambient air of Cologne (Germany). Atmospheric Environment, 35, pp. 5525-5536. DOI: 10.1016/S1352-2310(01)00234-5

51. Yang L., Zhu G., Pan H., Shi P., Li J., Liu Y. and Tong H. (2017). Surface dust heavy metals in the major cities, China. Environmental Earth Sciences, 76(757), pp. 1-4. DOI: 10.1007/s12665-017-7084-9

52. Yisa J., Jacob J. and Onoyima C. (2011). Identification of sources of heavy metals pollution in road deposited sediments using multivariate statistical analysis. Journal of Emerging Trends in Engineering and Applied Sciences, 2(4), pp. 658-663.


For citations:

Kasimov N.S., Kosheleva N.E., Vlasov D.V., Nabelkina K.S., Ryzhov A.V. Physicochemical Properties of Road Dust in Moscow. GEOGRAPHY, ENVIRONMENT, SUSTAINABILITY. 2019;12(4):96-113.

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