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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">gesj</journal-id><journal-title-group><journal-title xml:lang="en">GEOGRAPHY, ENVIRONMENT, SUSTAINABILITY</journal-title><trans-title-group xml:lang="ru"><trans-title>GEOGRAPHY, ENVIRONMENT, SUSTAINABILITY</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2071-9388</issn><issn pub-type="epub">2542-1565</issn><publisher><publisher-name>Russian Geographical Society</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.24057/2071-9388-2019-58</article-id><article-id custom-type="elpub" pub-id-type="custom">gesj-906</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>SPECIAL ISSUE "Urban environmental geography: Mosсow and other megacities"</subject></subj-group></article-categories><title-group><article-title>Mercury Pollution In Snow Cover Around Thermal Power Plants In Cities (Omsk, Kemerovo, Tomsk Regions, Russia)</article-title><trans-title-group xml:lang="ru"><trans-title></trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Talovskaya</surname><given-names>Anna V.</given-names></name></name-alternatives><bio xml:lang="en"><p>School of Earth Sciences and Engineering</p><p>30 Lenin Ave., 634050, Tomsk</p></bio><email xlink:type="simple">talovskaj@yandex.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Yazikov</surname><given-names>Egor G.</given-names></name></name-alternatives><bio xml:lang="en"><p>School of Earth Sciences and Engineering</p><p>30 Lenin Ave., 634050, Tomsk</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Osipova</surname><given-names>Nina A.</given-names></name></name-alternatives><bio xml:lang="en"><p>School of Earth Sciences and Engineering</p><p>30 Lenin Ave., 634050, Tomsk</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Lyapina</surname><given-names>Elena E.</given-names></name></name-alternatives><bio xml:lang="en"><p>Laboratory of Physics of Climatic Systems</p><p>10/3 Academichesky Ave., 634055, Tomsk</p></bio><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Litay</surname><given-names>Victoria V.</given-names></name></name-alternatives><bio xml:lang="en"><p>40 Korolev, 630015, Novosibirsk</p></bio><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Metreveli</surname><given-names>George</given-names></name></name-alternatives><bio xml:lang="en"><p>Group of Environmental and Soil Chemistry, Institute for Environmental Sciences</p><p>Fortstrasse 7, D-76829 Landau, Germany</p></bio><xref ref-type="aff" rid="aff-4"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="western" xml:lang="en"><surname>Kim</surname><given-names>Junbeum</given-names></name></name-alternatives><bio xml:lang="en"><p>CREIDD Research Centre on Environmental Studies &amp; Sustainability, Department of Humanities, Environment &amp; Information Technology (HETIC)</p><p>UMR 6281, France</p></bio><xref ref-type="aff" rid="aff-5"/></contrib></contrib-group><aff xml:lang="en" id="aff-1"><institution>National Research Tomsk Polytechnic University</institution><country>Russian Federation</country></aff><aff xml:lang="en" id="aff-2"><institution>Institute of Monitoring of Climatic and Ecological Systems of the Siberian Branch of the RAS</institution><country>Russian Federation</country></aff><aff xml:lang="en" id="aff-3"><institution>Siberian Geotechnical Service</institution><country>Russian Federation</country></aff><aff xml:lang="en" id="aff-4"><institution>University of Koblenz-Landau</institution><country>Germany</country></aff><aff xml:lang="en" id="aff-5"><institution>University of Technology of Troyes</institution><country>France</country></aff><pub-date pub-type="collection"><year>2019</year></pub-date><pub-date pub-type="epub"><day>30</day><month>12</month><year>2019</year></pub-date><volume>12</volume><issue>4</issue><fpage>132</fpage><lpage>147</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Talovskaya A.V., Yazikov E.G., Osipova N.A., Lyapina E.E., Litay V.V., Metreveli G., Kim J., 2019</copyright-statement><copyright-year>2019</copyright-year><copyright-holder xml:lang="ru">Talovskaya A.V., Yazikov E.G., Osipova N.A., Lyapina E.E., Litay V.V., Metreveli G., Kim J.</copyright-holder><copyright-holder xml:lang="en">Talovskaya A.V., Yazikov E.G., Osipova N.A., Lyapina E.E., Litay V.V., Metreveli G., Kim J.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://ges.rgo.ru/jour/article/view/906">https://ges.rgo.ru/jour/article/view/906</self-uri><abstract><p>Although snow cover is studied as an efficient scavenger for atmospheric mercury (Hg), up to now little is known about Hg behaviour in urban snow cover impacted by thermal power plants (TPPs) during the winter heating season. This study is focused on quantification of Hg in the particulate phase in snow cover and estimation of atmospheric particulate Hg (HgP) depositional fluxes around urban TPPs in cities of Omsk, Kemerovo, Yurga, Tomsk (the south part of Western Siberia, Russia) to provide new insight into Hg occurrence in urban snow. The results demonstrate that the mean Hg content in the particulate phase of snow varied from 0.139 to 0.205mg kg-1, possibly depending on thermal power of TPPs and fuel type used. The estimated mean atmospheric HgP depositional fluxes ranged from 6.6 to 73.1 mg km-2 d-1. Around thermal power plants atmospheric HgP depositional flux was controlled by particulate load. Higher Hg contents in the particulate phase of snow and higher atmospheric HgP depositional fluxes observed in relation to the background values, as well as high enrichment factors determined for Hg in the particulate phase of snow relative to the mean Hg content in the Earth’s crust showed that the snow pollution with Hg is of anthropogenic origin. The coexistence of Hg and S observed for the particulate phase of snow indicated the possible presence of mercury sulfide in this phase. The parameters like Hg content in the particulate phase of snow and HgP atmospheric flux can be used as markers for the identification of coal combustion emission sources.</p></abstract><kwd-group xml:lang="en"><kwd>snow cover</kwd><kwd>particulate mercury</kwd><kwd>coal combustion</kwd><kwd>deposition</kwd><kwd>HgP quantification</kwd></kwd-group><funding-group><funding-statement xml:lang="en">The experimental procedures were carried out at Tomsk Polytechnic University within the  framework  of  Tomsk  Polytechnic University Competitiveness Enhancement Program Grant in the Group of Top Level World Research and Academic Institutions. This work was partially supported by the Russian Foundation for Basic Research (grant number 16-45-700184p_a, 2016–2018) and in the framework of the state budget theme No. AAAA-A17-117013050031-8. We are grateful Sergey Ilenok for his assistance in SEM-EDX analysis and Ekaterina Filimonenko for her help in Hg measurements (Uranium Geology International Centre, TPU), Raisa Abramova and Muriel Whitchurch for their comments during the manuscript preparation.</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Antonova A.M., Vorobev A.V., Vorobev V.A., Dutova E.M., Pokrovskiy V.D. (2019). Modelling distribution of contaminating substances of electric power emissions in the atmosphere on the basis of the SKAT programming complex. Bulletin of the Tomsk Polytechnic University, Geo Assets Engineering, 330(6), pp. 174–186.</mixed-citation><mixed-citation xml:lang="en">Antonova A.M., Vorobev A.V., Vorobev V.A., Dutova E.M., Pokrovskiy V.D. (2019). Modelling distribution of contaminating substances of electric power emissions in the atmosphere on the basis of the SKAT programming complex. Bulletin of the Tomsk Polytechnic University, Geo Assets Engineering, 330(6), pp. 174–186.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Antonovich V.V., Antokhin P.N., Arshinov M.Y., Belan B.D., Balin Y.S., Davydov D.K., Ivlev G.A., Kozlov A.V., Kozlov V.S., Kokhanenko G.P., Novoselov M.M., Panchenko M.V., Penner I.E., Pestunov D.A., Savkin D.E., Simonenkov D.V., Tolmachev G.N., Fofonov A.V., Chernov D.G., Smargunov V.P., Yausheva E.P., Paris J.-D., Ancellet G., Law K.S., Pelon J., Machida T., and Sasakawa M. (2018). Station for the comprehensive monitoring of the atmosphere at Fonovaya Observatory, West Siberia: Current status and future needs. In: Proc. of SPIE, 24th International Symposium on Atmospheric and Ocean Optics: Atmospheric Physics, Volume 10833. Available at: https://doi.org/10.1117/12.2504388</mixed-citation><mixed-citation xml:lang="en">Antonovich V.V., Antokhin P.N., Arshinov M.Y., Belan B.D., Balin Y.S., Davydov D.K., Ivlev G.A., Kozlov A.V., Kozlov V.S., Kokhanenko G.P., Novoselov M.M., Panchenko M.V., Penner I.E., Pestunov D.A., Savkin D.E., Simonenkov D.V., Tolmachev G.N., Fofonov A.V., Chernov D.G., Smargunov V.P., Yausheva E.P., Paris J.-D., Ancellet G., Law K.S., Pelon J., Machida T., and Sasakawa M. (2018). Station for the comprehensive monitoring of the atmosphere at Fonovaya Observatory, West Siberia: Current status and future needs. In: Proc. of SPIE, 24th International Symposium on Atmospheric and Ocean Optics: Atmospheric Physics, Volume 10833. Available at: https://doi.org/10.1117/12.2504388</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Arduzov S.I., Osipova N.A., Zaitseva O.P. and Belaya E.V. (2015). Geochemistry of Hg in Siberian coals. In: Proc. of 2d International symposium on mercury in biosphere: Ecological and geochemical approach, held 21–25 September 2015 in Novosibirsk, Russia, pp. 27–31 (in Russian)</mixed-citation><mixed-citation xml:lang="en">Arduzov S.I., Osipova N.A., Zaitseva O.P. and Belaya E.V. (2015). Geochemistry of Hg in Siberian coals. In: Proc. of 2d International symposium on mercury in biosphere: Ecological and geochemical approach, held 21–25 September 2015 in Novosibirsk, Russia, pp. 27–31 (in Russian)</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Baltrėnaitė E., Baltrėnas P., Lietuvninkas A., Šerevičienė V. and Zuokaitė E. (2014). Integrated evaluation of aerogenic pollution by air-transported heavy metals (Pb, Cd, Ni, Zn, Mn and Cu) in the analysis of the main deposit media. Environmental Science and Pollution Research, 21, pp. 299–313.</mixed-citation><mixed-citation xml:lang="en">Baltrėnaitė E., Baltrėnas P., Lietuvninkas A., Šerevičienė V. and Zuokaitė E. (2014). Integrated evaluation of aerogenic pollution by air-transported heavy metals (Pb, Cd, Ni, Zn, Mn and Cu) in the analysis of the main deposit media. Environmental Science and Pollution Research, 21, pp. 299–313.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Boutron C.F., Vandal G.M., Fitzgerald W.F. and Ferrari C.P. (1998). A forty year record of mercury in central Greenland snow. Geophysical Research Letters, 25, pp. 3315–3318.</mixed-citation><mixed-citation xml:lang="en">Boutron C.F., Vandal G.M., Fitzgerald W.F. and Ferrari C.P. (1998). A forty year record of mercury in central Greenland snow. Geophysical Research Letters, 25, pp. 3315–3318.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Brzezinska-Paudyn A., Van Loon J.C. and Balicki M.R. (1986). Multielement analysis and mercury speciation in atmospheric samples from the Toronto area. Water, Air, &amp; Soil Pollution, 27, pp. 45–56.</mixed-citation><mixed-citation xml:lang="en">Brzezinska-Paudyn A., Van Loon J.C. and Balicki M.R. (1986). Multielement analysis and mercury speciation in atmospheric samples from the Toronto area. Water, Air, &amp; Soil Pollution, 27, pp. 45–56.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Davidson C.I., Bergin M.H., and Kuhn H.D. (1996). The deposition of particles and gases to ice sheets. In: E.R. Wolff, R.C. Bales, ed., Chemical exchange between the atmosphere and polar snow, Berlin: Springer. NATO ASI Series I, 43, pp. 275–306.</mixed-citation><mixed-citation xml:lang="en">Davidson C.I., Bergin M.H., and Kuhn H.D. (1996). The deposition of particles and gases to ice sheets. In: E.R. Wolff, R.C. Bales, ed., Chemical exchange between the atmosphere and polar snow, Berlin: Springer. NATO ASI Series I, 43, pp. 275–306.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Douglas T.A., Sturm M., Blum J.D., Polashenski C., Stuefer S., Hiemstra C., Steffen A., Filhol S. and Prevost R. (2017). A pulse of mercury and major ions in snowmelt runoff from a small Arctic Alaska Watershed. Environmental Science &amp; Technology, 51, pp. 11145−11155.</mixed-citation><mixed-citation xml:lang="en">Douglas T.A., Sturm M., Blum J.D., Polashenski C., Stuefer S., Hiemstra C., Steffen A., Filhol S. and Prevost R. (2017). A pulse of mercury and major ions in snowmelt runoff from a small Arctic Alaska Watershed. Environmental Science &amp; Technology, 51, pp. 11145−11155.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Ferrari C.P., Dommergue A., Veysseyre A., Planchon F. and Boutron C.F. (2002). Mercury speciation in the French seasonal snow cover. Science of the Total Environment, 287(1–2), pp. 61–69.</mixed-citation><mixed-citation xml:lang="en">Ferrari C.P., Dommergue A., Veysseyre A., Planchon F. and Boutron C.F. (2002). Mercury speciation in the French seasonal snow cover. Science of the Total Environment, 287(1–2), pp. 61–69.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Filimonenko E.A., Lyapina E.E., Talovskaya A.V. and Parygina I.A. (2014). Eco-geochemical peculiarities of mercury content in solid residue of snow in the industrial enterprises impacted areas of Tomsk. In: Proc. of SPIE 9292, 20th International Symposium on Atmospheric and Ocean Optics: Atmospheric Physics, Volume 929231. Available at: https:// doi.org/10.1117/12.2075637</mixed-citation><mixed-citation xml:lang="en">Filimonenko E.A., Lyapina E.E., Talovskaya A.V. and Parygina I.A. (2014). Eco-geochemical peculiarities of mercury content in solid residue of snow in the industrial enterprises impacted areas of Tomsk. In: Proc. of SPIE 9292, 20th International Symposium on Atmospheric and Ocean Optics: Atmospheric Physics, Volume 929231. Available at: https:// doi.org/10.1117/12.2075637</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Filimonova L.M., Parshin A.V., and Bychinskii V.A. (2015) Air pollution assessment in the area of aluminum production by snow geochemical survey. Russian Meteorology and Hydrology, 40 (10), pp. 691–698.</mixed-citation><mixed-citation xml:lang="en">Filimonova L.M., Parshin A.V., and Bychinskii V.A. (2015) Air pollution assessment in the area of aluminum production by snow geochemical survey. Russian Meteorology and Hydrology, 40 (10), pp. 691–698.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Fitzgerald W.F., Mason R.P., and Vandal G.M. (1991). Atmospheric cycling and air-water exchange of mercury over mid-continental lacustrine regions. Water, Air, &amp; Soil Pollution, 56, pp. 745–764.</mixed-citation><mixed-citation xml:lang="en">Fitzgerald W.F., Mason R.P., and Vandal G.M. (1991). Atmospheric cycling and air-water exchange of mercury over mid-continental lacustrine regions. Water, Air, &amp; Soil Pollution, 56, pp. 745–764.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Galbreath K.C. and Zygarlicke C.J. (2000). Mercury transformation in coal combustion flue gas. Fuel Processing Technology, 65–66, pp. 289–310.</mixed-citation><mixed-citation xml:lang="en">Galbreath K.C. and Zygarlicke C.J. (2000). Mercury transformation in coal combustion flue gas. Fuel Processing Technology, 65–66, pp. 289–310.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Galitskaya I.V. and Rumyantseva N.A. (2012). Snow-cover contamination in urban territories (Lefortovo district Moscow). Annals Glaciology, 53 (61), pp. 23–26.</mixed-citation><mixed-citation xml:lang="en">Galitskaya I.V. and Rumyantseva N.A. (2012). Snow-cover contamination in urban territories (Lefortovo district Moscow). Annals Glaciology, 53 (61), pp. 23–26.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Gao Y., Yang C., Maa J. and Yinc M. (2018). Characteristics of the trace elements and arsenic, iodine and bromine species in snow in east-central China. Atmospheric Environment, 174, pp.43–53.</mixed-citation><mixed-citation xml:lang="en">Gao Y., Yang C., Maa J. and Yinc M. (2018). Characteristics of the trace elements and arsenic, iodine and bromine species in snow in east-central China. Atmospheric Environment, 174, pp.43–53.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Gratz L.E. and Keeler G.J. (2011). Sources of mercury in precipitation to Underhill, VT. Atmospheric Environment, 45, pp. 5440–5449.</mixed-citation><mixed-citation xml:lang="en">Gratz L.E. and Keeler G.J. (2011). Sources of mercury in precipitation to Underhill, VT. Atmospheric Environment, 45, pp. 5440–5449.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Grebenshchikova V.I., Efimova N.V., and Doroshkov A.A. (2017). Chemical composition of snow and soil in Svirsk city (Irkutsk Region, Pribaikal’e). Environmental Earth Sciences, 76 (20), pp. 712.</mixed-citation><mixed-citation xml:lang="en">Grebenshchikova V.I., Efimova N.V., and Doroshkov A.A. (2017). Chemical composition of snow and soil in Svirsk city (Irkutsk Region, Pribaikal’e). Environmental Earth Sciences, 76 (20), pp. 712.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Grigor’ev N.A. (2009). Distribution of chemical elements in the upper continental crust. Yekaterinburg: UrO RAN (in Russian)</mixed-citation><mixed-citation xml:lang="en">Grigor’ev N.A. (2009). Distribution of chemical elements in the upper continental crust. Yekaterinburg: UrO RAN (in Russian)</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Gustaytis M.A., Myagkaya I.N., and Chumbaev A.S. (2018.) Hg in snow cover and snowmelt waters in high-sulfide tailing regions (Ursk tailing dump site, Kemerovo region, Russia). Chemosphere, 202, pp. 446–459.</mixed-citation><mixed-citation xml:lang="en">Gustaytis M.A., Myagkaya I.N., and Chumbaev A.S. (2018.) Hg in snow cover and snowmelt waters in high-sulfide tailing regions (Ursk tailing dump site, Kemerovo region, Russia). Chemosphere, 202, pp. 446–459.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Huang J., Kang S., Guo J., Sillanpaa M., Zhang Q., Qin X., Du W. and Tripathee L. (2014). Mercury distribution and variation on a high-elevation mountain glacier on the northern boundary of the Tibetan Plateau. Atmospheric Environment, 96, pp. 27–36.</mixed-citation><mixed-citation xml:lang="en">Huang J., Kang S., Guo J., Sillanpaa M., Zhang Q., Qin X., Du W. and Tripathee L. (2014). Mercury distribution and variation on a high-elevation mountain glacier on the northern boundary of the Tibetan Plateau. Atmospheric Environment, 96, pp. 27–36.</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Kasimov N.S., Kosheleva N.E., Vlasov D.V. and Terskaya E.V. (2012). Geochemistry of snow cover within the eastern district of Moscow. Vestnik Moskovskogo Unviersiteta, Seriya Geografiya. 4, pp. 14–24 (in Russian with English summary)</mixed-citation><mixed-citation xml:lang="en">Kasimov N.S., Kosheleva N.E., Vlasov D.V. and Terskaya E.V. (2012). Geochemistry of snow cover within the eastern district of Moscow. Vestnik Moskovskogo Unviersiteta, Seriya Geografiya. 4, pp. 14–24 (in Russian with English summary)</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Kim P-R., Han Y-J., Holsen T.M. and Yic S-M. (2012). Atmospheric particulate mercury: Concentrations and size distributions. Atmospheric Environment, 61, pp. 94–102.</mixed-citation><mixed-citation xml:lang="en">Kim P-R., Han Y-J., Holsen T.M. and Yic S-M. (2012). Atmospheric particulate mercury: Concentrations and size distributions. Atmospheric Environment, 61, pp. 94–102.</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Lyapina E.E., Golovatskaya E.A., Ippolitov I.I. (2009). Investigation of mercury content in natural objects of West Siberia. Contemporary Problems of Ecology, 2(1), pp. 1–5.</mixed-citation><mixed-citation xml:lang="en">Lyapina E.E., Golovatskaya E.A., Ippolitov I.I. (2009). Investigation of mercury content in natural objects of West Siberia. Contemporary Problems of Ecology, 2(1), pp. 1–5.</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Marusczak N., Larose C., Dommergue D., Yumvihoze E., Lean D., Nedjai R. and Ferrari C. (2011). Total mercury and methylmercury in high altitude surface snow from the French Alps. Sci. Science of the Total Environment, 409, pp. 3949–3954.</mixed-citation><mixed-citation xml:lang="en">Marusczak N., Larose C., Dommergue D., Yumvihoze E., Lean D., Nedjai R. and Ferrari C. (2011). Total mercury and methylmercury in high altitude surface snow from the French Alps. Sci. Science of the Total Environment, 409, pp. 3949–3954.</mixed-citation></citation-alternatives></ref><ref id="cit25"><label>25</label><citation-alternatives><mixed-citation xml:lang="ru">Nelson S.J., Fernandez I.J., and Kahl J.S. (2010). A review of mercury concentration and deposition in snow in eastern temperate North America. In: Hydrological Processes Special Issue: Eastern Snow Conference, 24 (14), pp. 1971–1980. Available at: https://doi.org/10.1002/hyp.7660</mixed-citation><mixed-citation xml:lang="en">Nelson S.J., Fernandez I.J., and Kahl J.S. (2010). A review of mercury concentration and deposition in snow in eastern temperate North America. In: Hydrological Processes Special Issue: Eastern Snow Conference, 24 (14), pp. 1971–1980. Available at: https://doi.org/10.1002/hyp.7660</mixed-citation></citation-alternatives></ref><ref id="cit26"><label>26</label><citation-alternatives><mixed-citation xml:lang="ru">Nelson S.J., Johnson K.B., Kahl J.S., Haines T.A. and Fernandez I.J. (2007). Mass balances of mercury and nitrogen in burned and unburned forested watersheds at Acadia National Park, Maine, USA. Environmental Monitoring and Assessment, 126, pp. 69–80.</mixed-citation><mixed-citation xml:lang="en">Nelson S.J., Johnson K.B., Kahl J.S., Haines T.A. and Fernandez I.J. (2007). Mass balances of mercury and nitrogen in burned and unburned forested watersheds at Acadia National Park, Maine, USA. Environmental Monitoring and Assessment, 126, pp. 69–80.</mixed-citation></citation-alternatives></ref><ref id="cit27"><label>27</label><citation-alternatives><mixed-citation xml:lang="ru">Osipova N.A., Filimonenko K.A., Talovskaya A.V. and Yazikov E.G. (2015). Geochemical approach to human health risk assessment of inhaled trace elements in the vicinity of industrial enterprises in Tomsk, Russia. Human and Ecological Risk Assessment, 21, pp. 1664–1685.</mixed-citation><mixed-citation xml:lang="en">Osipova N.A., Filimonenko K.A., Talovskaya A.V. and Yazikov E.G. (2015). Geochemical approach to human health risk assessment of inhaled trace elements in the vicinity of industrial enterprises in Tomsk, Russia. Human and Ecological Risk Assessment, 21, pp. 1664–1685.</mixed-citation></citation-alternatives></ref><ref id="cit28"><label>28</label><citation-alternatives><mixed-citation xml:lang="ru">Pope C.A. and Dockery D.W. (2006). Health effects of fine particulate air pollution: Lines that connect. Journal of the Air &amp; Waste Management Association, 56(6), pp. 709−742.</mixed-citation><mixed-citation xml:lang="en">Pope C.A. and Dockery D.W. (2006). Health effects of fine particulate air pollution: Lines that connect. Journal of the Air &amp; Waste Management Association, 56(6), pp. 709−742.</mixed-citation></citation-alternatives></ref><ref id="cit29"><label>29</label><citation-alternatives><mixed-citation xml:lang="ru">Raputa V.F., Kokovkin V.V., Shuvaeva O.V. and Morozov S.V. (2010). Experimental study and numerical analysis of the pollution in the area of highway according to the snow cover composistion. In: Proc. of International Conference on Energy and Development, Environment and Biomedicine, pp. 104–108.</mixed-citation><mixed-citation xml:lang="en">Raputa V.F., Kokovkin V.V., Shuvaeva O.V. and Morozov S.V. (2010). Experimental study and numerical analysis of the pollution in the area of highway according to the snow cover composistion. In: Proc. of International Conference on Energy and Development, Environment and Biomedicine, pp. 104–108.</mixed-citation></citation-alternatives></ref><ref id="cit30"><label>30</label><citation-alternatives><mixed-citation xml:lang="ru">Russian State Standard 12026-76 for Laboratory filter paper. Specifications. Available at: http://meganorm.ru/Data2/1/4294838/4294838884.pdf [Accessed 15 January 2013] (in Russian)</mixed-citation><mixed-citation xml:lang="en">Russian State Standard 12026-76 for Laboratory filter paper. Specifications. Available at: http://meganorm.ru/Data2/1/4294838/4294838884.pdf [Accessed 15 January 2013] (in Russian)</mixed-citation></citation-alternatives></ref><ref id="cit31"><label>31</label><citation-alternatives><mixed-citation xml:lang="ru">Russian State Standard 25543-88. Brown coals, hard coals and anthracites. Classification according to genetic and technological parameters. Available at: http://www.internet-law.ru/gosts/gost/7460 [Accessed 15 July 2018] (in Russian)</mixed-citation><mixed-citation xml:lang="en">Russian State Standard 25543-88. Brown coals, hard coals and anthracites. Classification according to genetic and technological parameters. Available at: http://www.internet-law.ru/gosts/gost/7460 [Accessed 15 July 2018] (in Russian)</mixed-citation></citation-alternatives></ref><ref id="cit32"><label>32</label><citation-alternatives><mixed-citation xml:lang="ru">Russian State Standard for air pollution control. RD 52.04.186-89. Available at: http://docs.cntd.ru/document/1200036406 [Accessed 15 Dec. 2012] (in Russian)</mixed-citation><mixed-citation xml:lang="en">Russian State Standard for air pollution control. RD 52.04.186-89. Available at: http://docs.cntd.ru/document/1200036406 [Accessed 15 Dec. 2012] (in Russian)</mixed-citation></citation-alternatives></ref><ref id="cit33"><label>33</label><citation-alternatives><mixed-citation xml:lang="ru">Saur E. and Juste C. (1994). Enrichment of trace elements from long-range aerosol transport in sandy podzolic soils of Southwest France. Water, Air, &amp; Soil Pollution, 73, pp. 235–246.</mixed-citation><mixed-citation xml:lang="en">Saur E. and Juste C. (1994). Enrichment of trace elements from long-range aerosol transport in sandy podzolic soils of Southwest France. Water, Air, &amp; Soil Pollution, 73, pp. 235–246.</mixed-citation></citation-alternatives></ref><ref id="cit34"><label>34</label><citation-alternatives><mixed-citation xml:lang="ru">Schroeder W.H. and Munthe J. (1998). Atmospheric mercury an overview. Atmospheric Environment, 32, pp. 809–822.</mixed-citation><mixed-citation xml:lang="en">Schroeder W.H. and Munthe J. (1998). Atmospheric mercury an overview. Atmospheric Environment, 32, pp. 809–822.</mixed-citation></citation-alternatives></ref><ref id="cit35"><label>35</label><citation-alternatives><mixed-citation xml:lang="ru">Shevchenko V., Lisitzin A., Vinogradova A. and Stein R. (2003). Heavy metals in aerosols over the seas of the Russian Arctic. Science of the Total Environment, 306 (1–3), pp. 11–25.</mixed-citation><mixed-citation xml:lang="en">Shevchenko V., Lisitzin A., Vinogradova A. and Stein R. (2003). Heavy metals in aerosols over the seas of the Russian Arctic. Science of the Total Environment, 306 (1–3), pp. 11–25.</mixed-citation></citation-alternatives></ref><ref id="cit36"><label>36</label><citation-alternatives><mixed-citation xml:lang="ru">Siudek P. (2016). Distribution and variability of total mercury in snow cover – a case study from a semi-urban site in Poznan. Poland. Environmental Science and Pollution Research, 23, pp. 24316–24326.</mixed-citation><mixed-citation xml:lang="en">Siudek P. (2016). Distribution and variability of total mercury in snow cover – a case study from a semi-urban site in Poznan. Poland. Environmental Science and Pollution Research, 23, pp. 24316–24326.</mixed-citation></citation-alternatives></ref><ref id="cit37"><label>37</label><citation-alternatives><mixed-citation xml:lang="ru">Siudek P., Falkowska L., Frankowski M. and Siepak J. (2014). An investigation of atmospheric mercury accumulated in the snow cover from the urbanized coastal zone of the Baltic Sea, Poland. Atmospheric Environment, 95, pp. 10–19.</mixed-citation><mixed-citation xml:lang="en">Siudek P., Falkowska L., Frankowski M. and Siepak J. (2014). An investigation of atmospheric mercury accumulated in the snow cover from the urbanized coastal zone of the Baltic Sea, Poland. Atmospheric Environment, 95, pp. 10–19.</mixed-citation></citation-alternatives></ref><ref id="cit38"><label>38</label><citation-alternatives><mixed-citation xml:lang="ru">Talovskaya A.V., Filimonenko E.A., Osipova N.A., Lyapina E.E. and Yazikov E.G. (2014). Toxic elements (As, Se, Cd, Hg, Pb) and their mineral and technogenic formations in the snow cover in the vicinity of the industrial enterprises of Tomsk. XVIII International Scientific Symposium in Honour of Academician M. A. Usov: PGON2014 IOP Publishing IOP Conference Series of Earth Environment Scicience, Volume 21, 012042. Available at: https://doi.org/10.1088/1755e1315/21/1/012042</mixed-citation><mixed-citation xml:lang="en">Talovskaya A.V., Filimonenko E.A., Osipova N.A., Lyapina E.E. and Yazikov E.G. (2014). Toxic elements (As, Se, Cd, Hg, Pb) and their mineral and technogenic formations in the snow cover in the vicinity of the industrial enterprises of Tomsk. XVIII International Scientific Symposium in Honour of Academician M. A. Usov: PGON2014 IOP Publishing IOP Conference Series of Earth Environment Scicience, Volume 21, 012042. Available at: https://doi.org/10.1088/1755e1315/21/1/012042</mixed-citation></citation-alternatives></ref><ref id="cit39"><label>39</label><citation-alternatives><mixed-citation xml:lang="ru">Talovskaya A.V., Filimonenko E.A., Osipova N.A. and Yazikov E.G. (2012). Mercury in dust aerosols in the territory of Tomsk. Safety in Technosphere, 2, pp. 30–34 (in Russian with English summary).</mixed-citation><mixed-citation xml:lang="en">Talovskaya A.V., Filimonenko E.A., Osipova N.A. and Yazikov E.G. (2012). Mercury in dust aerosols in the territory of Tomsk. Safety in Technosphere, 2, pp. 30–34 (in Russian with English summary).</mixed-citation></citation-alternatives></ref><ref id="cit40"><label>40</label><citation-alternatives><mixed-citation xml:lang="ru">Taraškevičius R., Zinkut R., Gedminien L., Stankevičius Z. (2018). Hair geochemical composition of children from Vilnius kindergartens as an indicator of environmental conditions. Environmental Geochemistry and Health, 40(5), pp. 1817–1840.</mixed-citation><mixed-citation xml:lang="en">Taraškevičius R., Zinkut R., Gedminien L., Stankevičius Z. (2018). Hair geochemical composition of children from Vilnius kindergartens as an indicator of environmental conditions. Environmental Geochemistry and Health, 40(5), pp. 1817–1840.</mixed-citation></citation-alternatives></ref><ref id="cit41"><label>41</label><citation-alternatives><mixed-citation xml:lang="ru">Tchounwou P.B., Ayensu W.K., Ninashvili N. and Sutton D. (2003). Review: environmental exposure to mercury and its toxicopathologic implications for public health. Environmental toxicology, 18 (3), pp. 149–175.</mixed-citation><mixed-citation xml:lang="en">Tchounwou P.B., Ayensu W.K., Ninashvili N. and Sutton D. (2003). Review: environmental exposure to mercury and its toxicopathologic implications for public health. Environmental toxicology, 18 (3), pp. 149–175.</mixed-citation></citation-alternatives></ref><ref id="cit42"><label>42</label><citation-alternatives><mixed-citation xml:lang="ru">UNEP. (2013). Global mercury assessment 2013: sources, emissions, releases and environmental transport, UNEP Chemicals Branch, Geneva, Switzerland</mixed-citation><mixed-citation xml:lang="en">UNEP. (2013). Global mercury assessment 2013: sources, emissions, releases and environmental transport, UNEP Chemicals Branch, Geneva, Switzerland</mixed-citation></citation-alternatives></ref><ref id="cit43"><label>43</label><citation-alternatives><mixed-citation xml:lang="ru">Wiener J.G., Krabbenhoft D.P., Heinz G.H. and Scheuhammer A.M. (2003). Ecotoxicology of mercury. In: Hoffman DJ, Rattner BA, Burton GA, Cairns JS, ed., Handbook of ecotoxicology, Lewis Publ, Boca Raton, pp. 409–463.</mixed-citation><mixed-citation xml:lang="en">Wiener J.G., Krabbenhoft D.P., Heinz G.H. and Scheuhammer A.M. (2003). Ecotoxicology of mercury. In: Hoffman DJ, Rattner BA, Burton GA, Cairns JS, ed., Handbook of ecotoxicology, Lewis Publ, Boca Raton, pp. 409–463.</mixed-citation></citation-alternatives></ref><ref id="cit44"><label>44</label><citation-alternatives><mixed-citation xml:lang="ru">Wilhelm S.M. (2001). Mercury in petroleum and natural gas: estimation of emissions from production, processing, and combustion. In: EPA/600/R-01/066 (NTIS PB2001-109026), U.S. Environmental Protection Agency, Washington</mixed-citation><mixed-citation xml:lang="en">Wilhelm S.M. (2001). Mercury in petroleum and natural gas: estimation of emissions from production, processing, and combustion. In: EPA/600/R-01/066 (NTIS PB2001-109026), U.S. Environmental Protection Agency, Washington</mixed-citation></citation-alternatives></ref><ref id="cit45"><label>45</label><citation-alternatives><mixed-citation xml:lang="ru">Williamson B.J., Purvis O.W., Mikhailova I.N., Spiro B. and Udachin V. (2008). The lichen transplant methodology in the source apportionment of metal deposition around a copper smelter in the former mining town of Karabash, Russia. Environmental Monitoring and Assessment, 141 (1–3), pp. 227–236.</mixed-citation><mixed-citation xml:lang="en">Williamson B.J., Purvis O.W., Mikhailova I.N., Spiro B. and Udachin V. (2008). The lichen transplant methodology in the source apportionment of metal deposition around a copper smelter in the former mining town of Karabash, Russia. Environmental Monitoring and Assessment, 141 (1–3), pp. 227–236.</mixed-citation></citation-alternatives></ref><ref id="cit46"><label>46</label><citation-alternatives><mixed-citation xml:lang="ru">Xu M., Yan R., Zheng C., Qiao Y., Han J. and Sheng C. (2003). Status of trace element emission in a coal combustion process: a review. Fuel Processing Technology, 85, pp. 215– 237.</mixed-citation><mixed-citation xml:lang="en">Xu M., Yan R., Zheng C., Qiao Y., Han J. and Sheng C. (2003). Status of trace element emission in a coal combustion process: a review. Fuel Processing Technology, 85, pp. 215– 237.</mixed-citation></citation-alternatives></ref><ref id="cit47"><label>47</label><citation-alternatives><mixed-citation xml:lang="ru">Yanchenko N.I., Slutskii S.L., Baranov A.N. and Verkhoturov V.V. (2015). Dynamics of fluoride atmospheric fallouts in the Baikal region. Russian Meteorology and Hydrology, 40 (11), pp. 766–771.</mixed-citation><mixed-citation xml:lang="en">Yanchenko N.I., Slutskii S.L., Baranov A.N. and Verkhoturov V.V. (2015). Dynamics of fluoride atmospheric fallouts in the Baikal region. Russian Meteorology and Hydrology, 40 (11), pp. 766–771.</mixed-citation></citation-alternatives></ref><ref id="cit48"><label>48</label><citation-alternatives><mixed-citation xml:lang="ru">Zhang Y., Xiu G., Wu X., Moore C.W., Wang J., Cai J., Zhang D., Shi C. and Zhang R. (2013). Characterization of mercury contents in snow and potential sources, Shanghai, China. Science of the Total Environment, 449, pp. 434–442.</mixed-citation><mixed-citation xml:lang="en">Zhang Y., Xiu G., Wu X., Moore C.W., Wang J., Cai J., Zhang D., Shi C. and Zhang R. (2013). Characterization of mercury contents in snow and potential sources, Shanghai, China. Science of the Total Environment, 449, pp. 434–442.</mixed-citation></citation-alternatives></ref><ref id="cit49"><label>49</label><citation-alternatives><mixed-citation xml:lang="ru">Zharov Yu.N., Meitov E.S. and Sharova I.G .(1996). Valuable and toxic elements in traded coal of Russia. Handbook. Moscow: Nedra (in Russian)</mixed-citation><mixed-citation xml:lang="en">Zharov Yu.N., Meitov E.S. and Sharova I.G .(1996). Valuable and toxic elements in traded coal of Russia. Handbook. Moscow: Nedra (in Russian)</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
